Shock tube study of normal heptane first-stage ignition near 3.5 atm

Fuel-rich n-heptane oxidation: A shock tube and laser absorption study

The chemical kinetics of n-heptane (n-C 7 H 16 ) – an important reference compound for real fuels – oxidation are well studied at stoichiometric and lean conditions. However, there is only limited information on the n-heptane chemical kinetics in fuel-rich combustion. In order to verify the accuracy of chemical kinetic models at these conditions, the oxidation of rich n-heptane mixtures has bee...

Auto-ignition of aromatic and aliphatic Diesel fuel components: High-pressure shock-tube experiments and kinetic modeling for toluene and n-heptane

The auto-ignition of toluene and n-heptane as model fuels for Diesel fuel components have been studied in a highpressure shock tube under engine-relevant conditions. Toluene/air and n-heptane/air mixtures as well as toluene/nheptane/air (10/90% and 40/60% by volume) have been investigated over a wide temperature range (700 – 1200 K), = 1.0 and 0.5 and 40 bar behind reflected shock waves. A kine...

GLOBAL KINETICS FOR n-HEPTANE IGNITION AT HIGH PRESSURES

A kinetic mechanism of 1011 elementary reactions with 171 chemical species for n-heptane ignition is analysed and reduced to 4 global steps with adjusted rate coefficients to describe ignition at pressures around 40 atm. Two of these steps account for the high temperature branch and the other two for the low temperature branch of the ignition mechanism. The ignition delay time passes through a ...

Shock Tube Measurements of Iso-octane Ignition times and Oh Concentration Time Histories

Detailed Simulations of Shock-Bifurcation and Ignition of an Argon-diluted Hydrogen/Oxygen Mixture in a Shock Tube

Detailed simulations of the bifurcation and ignition of an Argon-diluted Hydrogen/Oxygen mixture in the two-stage weak ignition regime are performed. An adaptive meshrefinement (AMR) technique is employed to resolve all relevant physical scales that are associated with the viscous boundary-layer, the reaction front, and the shock-wave. A high-order hybrid WENO/central-differencing method is use...